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9780470277386

Molecular Recognition and Polymers Control of Polymer Structure and Self-Assembly

by ;
  • ISBN13:

    9780470277386

  • ISBN10:

    0470277386

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2008-09-02
  • Publisher: Wiley

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Summary

State-of-the-art techniques for tapping the vast potential of polymers The use of specific non-covalent interactions to control polymer structure and properties is a rapidly emerging field with applications in diverse disciplines. Molecular Recognition and Polymers covers the fundamental aspects and applications of molecular recognition?in the creation of novel polymeric materials for use in drug delivery, sensors, tissue engineering, molecular imprinting, and other areas. This reference begins by explaining the fundamentals of supramolecular polymers; it progresses to cover polymer formation and self-assembly with a wide variety of examples, and then includes discussions of biomolecular recognition using polymers. With chapters contributed by the foremost experts in their fields, this resource: * Provides an integrated resource for supramolecular chemistry, polymer science, and interfacial science * Covers advanced, state-of-the-art techniques used in the design and characterization of non-covalent interactions in polymers * Illustrates how to tailor the properties of polymeric materials for various applications Stand-alone chapters address specific applications independently for easy reference. This is a premier resource for graduate students and researchers in polymer chemistry, supramolecular chemistry, materials science, and physical organic chemistry.

Author Biography

Vincent Rotello is the Goessmann Professor in the Department of Chemistry at the University of Massachusetts, Amherst. His research emphasizes achieving a fundamental understanding of supramolecular chemistry and applying it to issues in biology and nanoscience including delivery, sensing, and devices.

S. Thayumanavan is a Professor in the Department of Chemistry at the University of Massachusetts, Amherst. His research focuses on the design and synthesis of novel macromolecules (dendrimers and polymers) that have applications in chemistry, biology, and materials science. Examples of these applications include catalysis and transport, drug and gene delivery, and light harvesting and sensory materials.

Table of Contents

List of Tables, Figures, Charts and Schemes
Dedication
Preface
Acknowledgements
Editor Bibliographies
List of Contributors
Fundamentals Of Supramolecular Polymers
A Brief Introduction to Supramolecular Chemistry in a Polymer Context
Introduction and Background
Main-chain versus Side-chain Supramolecular Polymers
References
Molecular Recognition Using Amphiphilic Macromolecules
Introduction
Amphiphilic Block Copolymers
Non-Specific Interactions
Specific Interactions
Amphiphilic Homopolymers
Container Properties
Amphiphilic Dendrimers
Conclusions
Acknowledgements
References
Supramolecular Control of Mechanical Properties in Single Molecules, Interfaces and Macroscopic Materials
Introduction and Background
Mechanical Properties of Linear Supramolecular Polymers
Mechanical Properties of Supramolecular Polymer Networks
Mechanical Properties in Supramolecular Polymers at Interfaces
Mechanical Forces and Supramolecular Interactions
Conclusions
References
Polymer Formation And Self-Assembly
Hydrogen Bond Functionalized Block Copolymers and Telechelic Oligomers
Scientific Rationale and Perspective
Hydrogen Bonding Interactions in Macromolecular Design
Fundamentals of Hydrogen Bonding
Performance Advantages of Hydrogen Bond Containing Polymers
Hydrogen Bond Containing Block Copolymers
Telechelic Hydrogen Bond Functional Polymers
Combining Hydrogen Bonding with other Non-Covalent Interactions
Reversible Attachment of Guest Molecules via Hydrogen Bonding
Conclusions and Summary
References
Non-Covalent Side-chain Modification
Introduction
Strategies Towards Noncovalent Side-Chain Functionalization of Polymeric Scaffolds
Noncovalent Multifunctionalization of the Side-Chains of Polymeric Scaffolds
Applications of Noncovalently Functionalized Side-Chain Copolymers
Conclusions and Outlook
Acknowledgements
References
Polymer-Mediated Assembly of Nanoparticles Using Engineered Interactions
Introduction
Design of Nanoparticles and Polymers
Self-Assembly Polymer-particle Nanocomposites
Conclusions and Outlook
References
Metallo-Supramolecular Polymers, Networks, and Gels
Introduction
Metal-Ligand Binding Motifs
Linear and Macrocyclic Main-Chain Metallo-Supramolecular Polymers
Metallo-Supramolecular Networks and Gels
Conclusion and Outlook.References
Polymeric Capsules: Catalysis and Drug Delivery
Introduction
Methods of Encapsulation
Catalyst Encapsulation
Drug Delivery with Microcapsules
Conclusion
References
Sequence-Specific Hydrogen-Bonded Units for Directed Association, Assembly and Ligation
Introduction
General Design: Information-Storing Molecular Duplexes Based on the Recombination of H-Bond Donors and Acceptors
Quadruply H-Bonded Duplexes with Sequence-Independent Stability
Tuning Binding Strength
Table of Contents provided by Publisher. All Rights Reserved.

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