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9780841239319

Separations for the Nuclear Fuel Cycle in the 21st Century

by ; ; ;
  • ISBN13:

    9780841239319

  • ISBN10:

    0841239312

  • Format: Hardcover
  • Copyright: 2006-07-13
  • Publisher: American Chemical Society

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Summary

This book constitutes the proceedings from a symposium titled Separations for the Nuclear Fuel Cycle in the 21st Century which was held in March 2004. This symposium focused on assessing the current state-of-the art in nuclear separations science and technology, and on identifying R&D directions required to enable nuclear separations to meet 21st Century demands for waste minimization, environment protection, safety, and security. Several recent developments have elevated the importance of this topic including: the potential effects of global warming caused by carbon dioxide emissions from burning of fossil fuels; rising demand for the electric power that is needed to raise the global standard of living; geopolitical issues such as those related to nuclear proliferation and nuclear terrorism. Although expansion of fission-based nuclear power would help reduce the potential for global warming, future development of the nuclear fuel cycle must be weighed against the issues of proliferation and management of irradiated fuel. Separations will play a central role in addressing these issues. The subject matter of this book is organized into five topical areas. These are: 1) current trends and direction to the future, 2) aqueous processing, 3) emerging separations systems, 4) actinide/lanthanide separations, and 5) solution-solid interactions. This collection of papers provides a snapshot of the current state of nuclear separations chemistry and can be used to help guide future directions in this critical technological field.

Table of Contents

Prefacep. xi
Current Trends and Direction to the Future
Significance of the Nuclear Fuel Cycle in the 21st Centuryp. 3
Twenty-First Century Approaches to Actinide Partitioningp. 21
Advanced Separation Technologies for Processing Spent Nuclear Fuel and the Potential Benefits to a Geologic Repositoryp. 41
Reprocessing Spent Nuclear Fuel with Supercritical Carbon Dioxidep. 57
Aqueous Processing
Dissolution of Irradiated Nuclear Fuel from the Big Rock Point Reactorp. 71
Advanced PUREX Flowsheets for Future Np and Pu Fuel Cycle Demandsp. 89
Haze Formation and Behavior in Liquid-Liquid Extraction Processesp. 103
Comparison of Uranyl Third-Phase Formation in 30% TBP-Nitric Acid in Dodecane and HPT Using UV-Visible Spectroscopyp. 119
A New Interpretation of Third-Phase Formation in the Solvent Extraction of Actinides by TBPp. 135
The Interaction of Ammonium Carbamate with Uranyl- and Molybdenum Containing Species Derived from PUREX Processingp. 151
Plutonium Peroxide in Process Chemistry: Oxidation State, Coordination Chemistry, and Solubilityp. 167
Crystallization of Uranium Complexes for Partitioning of Spent Nuclear Fuelp. 183
Emerging Separations Systems
Potential Application of Klaui Ligands in Actinide Separationsp. 201
Actinide, Lanthanide, and Fission Product Speciation and Electrochemistry in Ionic Meltsp. 219
Application of Ionic Liquids in Actinide and Fission Product Separations: Progress and Prospectsp. 233
Actinide-Lanthanide Separations
Use of Cyanex-301 for Separation of Am/Cm from Lanthanides in an Advanced Nuclear Fuel Cyclep. 251
Extraction Separation of Am(III) and Eu(III) with TPEN Isomers and Decanoic Acidp. 261
Solution-Solid Interactions
The Influence of Simple Organic Ligands on the Partitioning Mechanism of Trivalent Lanthanum to Goethitep. 277
Neptunium Association with Selected Uranyl Phases Anticipated in the Yucca Mountain Repositoryp. 293
Speciation and Solubility Modeling of Actinides in the Waste Isolation Pilot Plantp. 313
Author Indexp. 335
Subject Indexp. 337
Table of Contents provided by Ingram. All Rights Reserved.

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